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Kamis, 24 Januari 2013

Schrödinger gas model

Einstein suggested to Erwin Schrödinger that he might be able to reproduce the statistics of a Bose–Einstein gas by considering a box. Then to each possible quantum motion of a particle in a box associate an independent harmonic oscillator. Quantizing these oscillators, each level will have an integer occupation number, which will be the number of particles in it.
This formulation is a form of second quantization, but it predates modern quantum mechanics. Erwin Schrödinger applied this to derive the thermodynamic properties of a semiclassical ideal gas. Schrödinger urged Einstein to add his name as co-author, although Einstein declined the invitation.[105]

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